Question

£¨2010?Ì©ÖÝÈýÄ££©à­Áòƽ¿ÉÓÃÓÚ¾«Éñ¼²²¡µÄÖÎÁÆ£¬Æä½á¹¹Îª£º£¬ËüµÄºÏ³É·ÏßÈçÏ£º

ÒÑÖª£º£¨¢ñ£©·´Ó¦¢ÙΪȡ´ú·´Ó¦£»£¨¢ò£©AµÄϵͳÃüÃûΪ1£¬4-¶þäå-2-¶¡Ï©£®
Çë»Ø´ðÏÂÁÐÎÊÌ⣺
£¨1£©Ð´³ö·Ö×ÓʽΪC₁₃H₉NO₄SµÄÎïÖʵĽṹ¼òʽ

£®
£¨2£©ÎïÖÊÖгýÁòÃѼü£¨-S-£©Í⣬»¹º¬ÓеĹÙÄÜÍÅÃû³ÆΪ

°±»ù¡¢ôÈ»ù

£®
£¨3£©·´Ó¦¢ÛµÄÀàÐÍÊÇ

¼Ó³É·´Ó¦

·´Ó¦£¬·´Ó¦¢ÝµÄÄ¿µÄÊÇ

±£»¤Ì¼Ì¼Ë«¼ü£¬·ÀÖ¹±»ËáÐÔKMnO₄Ñõ»¯

£®
£¨4£©Ð´³ö·´Ó¦¢ÜµÄ»¯Ñ§·½³Ìʽ

BrCH₂CH=CHCH₂Br+2NaOH

¡÷

HOCH₂CH=CHCH₂OH+2NaBr

£®
£¨5£©ÎïÖÊBµÄͬ·ÖÒì¹¹ÌåÓжàÖÖ£¬ÆäÖмȺ¬ÓÐôÇ»ù£¬ÓÖº¬ÓÐÈ©»ùµÄͬ·ÖÒì¹¹ÌåÓÐ

5

ÖÖ£®
£¨6£©ÒÑÖª£º-SHµÄÐÔÖÊÓë-OHÏàËÆ£®ÎïÖÊÒ»¶¨Ìõ¼þÏÂÐγɾۺÏÎïµÄ½á¹¹¼òʽΪ

£®

Answer 1

·ÖÎö£ºÓÉ¿ÉÖªC₁₃H₉NO₄SµÄÎïÖʵĽṹ¼òʽΪ£¬ÓÉ·Ö×ÓʽΪC₄H₆µÄÌþӦΪCH₂=CH-CH=CH₂£¬Óëäå·¢Éú1£¬4¼Ó³É£¬Éú³ÉCH₂Br-CH=CH-CH₂Br£¨A£©£¬ÔÚNaOHÈÜÒºÖÐË®½âÉú³ÉOH-CH₂-CH=CH-CH₂-OH£¬ÓëHBr¼Ó³ÉÉú³ÉOH-CH₂-CH₂-CHBr-CH₂-OH£¬Ñõ»¯ºóÉú³ÉHOOC-CH₂-CHBr-COOH£¬·¢ÉúÏûÈ¥·´Ó¦Éú³É£¬
ÔòAΪCH₂Br-CH=CH-CH₂Br£¬BΪOH-CH₂-CH=CH-CH₂-OH£¬CΪOH-CH₂-CH₂-CHBr-CH₂-OH£¬DΪHOOC-CH₂-CHBr-COOH£»±»Ñõ»¯¿ÉÉú³É£¬ÓëÏõËá·¢ÉúÈ¡´ú·´Ó¦Éú³É£¬±»»¹Ô­Éú³É£¬½ø¶ø·¢ÉúËõ¾Û·´Ó¦¿ÉÉú³É£®

½â´ð£º½â£º£¨1£©ÓÉ¿ÉÖªC₁₃H₉NO₄SµÄÎïÖʵĽṹ¼òʽΪ£¬¹Ê´ð°¸Îª£º£»
£¨2£©Öл¹º¬ÓÐ-NO₂¡¢-COOH¹ÙÄÜÍÅ£¬·Ö±ðΪÏõ»ùºÍôÈ»ù£¬¹Ê´ð°¸Îª£º°±»ù¡¢ôÈ»ù£»
£¨3£©C₄H₆µÄÌþӦΪCH₂=CH-CH=CH₂£¬Óëäå·¢Éú1£¬4¼Ó³É£¬Éú³ÉCH₂Br-CH=CH-CH₂Br£¬·´Ó¦¢ÝµÄÄ¿µÄÊÇ·ÀÖ¹C=C±»ËáÐÔ¸ßÃÌËá¼ØÑõ»¯£¬Æðµ½±£»¤¹ÙÄÜÍŵÄ×÷Óã¬
¹Ê´ð°¸Îª£º¼Ó³É·´Ó¦£¬±£»¤Ì¼Ì¼Ë«¼ü£¬·ÀÖ¹±»ËáÐÔKMnO₄Ñõ»¯£»
£¨4£©AΪCH₂Br-CH=CH-CH₂Br£¬ÔÚ¼îÐÔÌõ¼þÏ·¢ÉúÈ¡´ú·´Ó¦Éú³ÉHOCH₂CH=CHCH₂OH£¬
·´Ó¦µÄ»¯Ñ§·½³ÌʽΪBrCH₂CH=CHCH₂Br+2NaOH

¡÷

HOCH₂CH=CHCH₂OH+2NaBr£¬
¹Ê´ð°¸Îª£ºBrCH₂CH=CHCH₂Br+2NaOH

¡÷

HOCH₂CH=CHCH₂OH+2NaBr£»
£¨5£©BΪOH-CH₂-CH=CH-CH₂-OH£¬¼Èº¬ÓÐôÇ»ù£¬ÓÖº¬ÓÐÈ©»ùµÄͬ·ÖÒì¹¹ÌåÓУº
CH₂£¨OH£©CH₂CH₂CHO¡¢CH₃CH£¨OH£©CH₂CHO¡¢CH₃CH₂CH£¨OH£©CHO¡¢HOCH₂CH£¨CH₃£©CHO¡¢CH₂C£¨OH£©£¨CH₃£©CHO£¬
ËùÒÔ¹²ÓÐ5ÖÖ£¬¹Ê´ð°¸Îª£º5£»
£¨6£©ÎïÖÊÔÚÒ»¶¨Ìõ¼þÏ·¢ÉúËõ¾Û·´Ó¦£¬ËùÒÔÆäËõ¾ÛÎïµÄ½á¹¹¼òʽΪ£º£¬
¹Ê´ð°¸Îª£º£®

µãÆÀ£º±¾Ì⿼²éÓлúÎïµÄºÏ³É£¬ÌâÄ¿ÄѶÈÖеȣ¬½â´ð±¾ÌâµÄ¹Ø¼üÊÇÄÜ°ÑÎÕÌâ¸øÐÅÏ¢£¬¸ù¾ÝÓлúÎïµÄ¹ÙÄÜÍÅÅжÏÓлúÎï¿ÉÄܾßÓеÄÐÔÖÊ£®