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—Did you look up the time of trains to Shanghai?
—Yes, the earliest train is  ________ to leave at 5:30 am.
A.likelyB.about
C.possibleD.due
D
选D。be due to do意为“应该…/预期的”;be about to do 不和时间状语连用;possible主语应为it;而likely与句意不合。
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